WebAug 15, 2016 · The straightforward synthesis of a new Cu(i) metal-rich small metallacycle is presented. This compound is luminescent in the solid state with an emission quantum yield of 72% at room temperature and displays a pronounced reversible red-shift of its emission spectra upon cooling. Quantum chemical calculations WebThe unique pore structure is caused by a variety of non-covalent interactions. The use of grinding or fuming and soaking to break or reconstruct the pore structure, i.e., tuning the weak interactions, significantly changes the bond lengths and angles of Cu ( i) complexes, resulting in differences in their luminescence colors.
Coprophilic Definition & Meaning Merriam-Webster Medical
WebMar 2, 2024 · Significantly, this work first explored the effect of intrinsic cuprophilic interactions of Cu (I)-based catalysts on the electrocatalytic performance of CO2RR and provides an important case... WebJul 22, 2024 · Based on the above considerations, a hexanuclear Cu cluster with strong cuprophilic interactions has been designed and utilized as a secondary building unit (SBU) to construct a stable metal-organic framework (MOF) electrocatalyst (NNU-50). human emotions and emotional intelligence
Ultrathin covalent and cuprophilic interaction-assembled …
WebIts structural changes are directly related to the high Cu ( I )–I chain structural flexibility, which allows the shortening of the Cu⋯Cu distances via cuprophilic interactions. Moreover, the control of size, defects, and CuI content allows modifying its emission and electrical conductivity. WebFinally, a density functional theory (DFT) study of the energetic features of several noncovalent interactions observed in the solid state has been analyzed and characterized using Bader’s theory of “atoms in molecules” and the cuprophilic interactions in complex 2 using natural bond orbital methodology. WebNov 7, 2016 · Indeed, mechanical constraints on the molecularly self-assembled structure induce changes at the molecular level by modification of the [Cu 4 I 4] inorganic cluster core geometry and in particular of the strength of the cuprophilic interactions. human emotions mod people playground